I've got all the James Bond themes. I've got Music from The Man From U.N.C.L.E. I've got the soundtracks from the first two Austin Powers movies.
Please comment with your favorite spy-related songs. These can be obvious or obscure (such as the "Lando's Palace" theme from The Empire Strikes Back). If you're worried the connection might be too obscure, explain why you think it's a good choice.